Rh-Catalyzed Anti-Markovnikov Hydrocyanation of Terminal AlkynesWe report the first highly stereo- and regioselective hydrocyanation of terminal alkynes to furnish...有机方法2017-05-214.0W+
The First Example of an Iodide-Catalyzed Oxidative Amination of HeteroarenesAn efficient transition-metal-free amination of benzoxazoles has been developed. With catalytic am...有机方法2017-05-153.6W+
Cyanation of Aryl Bromides with NaCN in Recyclable SolventsRational catalysis design on the basis of a detailed mechanistic understanding has been used to su...有机方法2017-05-143.6W+
Copper-Catalyzed Synthesis of Substituted Benzothiazoles An efficient and convenient method was developed for the formation of 2-substituted benzothiazoles...有机方法2017-05-133.7W+ #苯并噻唑
Palladium-Catalyzed Formylation of Aryl Halides with tert-Butyl IsocyanideA novel palladium-catalyzed formylation of aryl halides with isocyanide in the presence of Et3SiH...有机方法2017-05-133.7W+ #甲酰基
Ynamides as Racemization-Free Coupling Reagents for Amide and Peptide SynthesisA highly efficient, two-step, one-pot synthetic strategy for amides and peptides was developed by...有机方法2017-05-123.8W+
Hypervalent Iodine as Terminal Oxidant in Wacker-Type Oxidation of Terminal Olefins to Methyl KetoneA mimic of the Wacker process for C═O bond formation in terminal olefins can be initiated by a com...有机方法2017-05-084.0W+ #甲基酮
Cu-Mediated Chemoselective Trifluoromethylation of Benzyl BromidesCopper-mediated chemoselective trifluoromethylation at the benzylic position by the use of shelf-s...有机方法2017-05-085.0W+ #三氟甲基
Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of BenzylboronatesThe chemoselective Pd-catalyzed Suzuki–Miyaura cross-coupling reaction using a diborylmethane is r...有机方法2017-05-034.1W+ #benzylboronates
Rate Enhanced Olefin Cross-Metathesis Reactions: The Copper Iodide EffectCopper iodide has been shown to be an effective cocatalyst for the olefin cross-metathesis reactio...有机方法2017-04-114.2W+
Corey–Nicolaou大环内酯化反应 ω-羟基酸或更长链的羟基酸通过2,2’-吡啶二硫化物处理得到大环内酯的反应。此反应也被称为Corey–Nicolaou双活化法。环化阶段通常需要加热回流。加入AgBF4可以活化吡啶硫酯...有机方法2017-04-075.3W+ #macro-lactones
Shiina大环内酯化反应 羟基羧酸利用2-甲基-6-硝基苯甲酸酐(MNBA; Shiina试剂 ，催化量的缩合剂(DMAP, DMAPO, PPY, etc 和三级胺，在温和的条件下进行大环内酯化的反应。此反应是东京理科大...有机方法2017-04-075.2W+ #macro-lactones
