Synthesis of Substituted CyclopropanecarboxylatesThe room temperature palladium-catalyzed cross-coupling of aromatic and heteroaromatic halides with...有机方法2018-05-193.7W+ #cyclopropyl
Cross-Coupling of Amides with AlkylboranesA protocol for the nickel-catalyzed alkylation of amides was established. The use of alkylboranes...有机方法2018-05-123.7W+ #ketone
A Synthetic Approach to N-Aryl CarbamatesA mild and efficient synthesis of N-arylcarbamates was achieved by reacting azidoformates with bor...有机方法2018-05-054.2W+ #Chan–Lam
The Conversion of Amides to Esters with Meerwein'S ReagentAn efficient two step transformation of 1° and 2° amides to methyl and ethyl esters has been devel...有机方法2018-04-283.9W+ #ester
Chan–Lam Amination: A Mechanism-Inspired Solution to Boronic Ester ReactivityWe report an investigation of the Chan–Lam amination reaction. A combination of spectroscopy, comp...有机方法2018-04-264.5W+ #Chan–Lam
KI-AcCl体系选择性还原亚砜Several functionalized sulfoxides in the modafinil series, which bear another reducible function,...有机方法2018-04-024.0W+ #thioether
Synthesis of 1,1′-DiarylethanesBenzylic trichloroacetimidates are readily displaced by trimethylaluminum under Lewis acid promote...有机方法2018-03-314.1W+
Nickel-Mediated Chan–Lam CouplingAn efficient use of NiCl2·6H2O, for the cross-coupling of arylboronic acids with various N-nucleophi...有机方法2018-03-294.7W+ #Chan–Lam
酚类和含氮杂环的环丙基反应 Small molecules containing cyclopropane–heteroatom linkages are commonly needed in medicinal chemi...有机方法2018-03-284.6W+ #cyclopropylation #Chan–Lam
Pd/NaH催化体系用于醚和酯的脱苄基和脱烯丙基反应Herein we demonstrate simply that the addition of Pd(OAc 2 as a promotor switches the reactivity o...有机方法2018-03-286.0W+ #苄基
LiCl对于i-PrMgCl的加强作用 一般格式试剂制备可以通过卤代烃和镁直接进行氧化加成反应，也可以通过格式试剂间的交换进行制备。1931年，Pre ´vost首例报道了使用乙基格式试剂进行交换，但收率很差。只有使用芳基碘或者活化的芳基溴...有机方法2017-12-167.3W+
Oxidative Debenzylation of N-Benzyl Amides and O-Benzyl Ethers Using Alkali Metal BromideThe oxidative debenzylation of N-benzyl amides and O-benzyl ethers was promoted with high efficien...有机方法2017-11-083.8W+
