Boron-Catalyzed O-H Bond Insertion of α-Aryl α-Diazoesters in WaterA catalytic, metal-free O-H bond insertion of α-diazoesters in water in the presence of B(C6F5 3·nH2...有机方法2019-08-103.8W+
Preparation of 5-Aryl-2-Alkyltetrazoles with Aromatic AldehydesA variety of 5-aryl-2-methyltetrazoles and 5-aryl-2-benzyltetrazoles were directly prepared in goo...有机方法2019-07-153.7W+ #tetrazole
Chan-Evans-Lam Amination of Boronic Acid Pinacol (BPin) Esters: Overcoming the Aryl Amine ProblemThe Chan-Evans-Lam reaction is a valuable C-N bond forming process. However, aryl boronic acid pin...有机方法2019-07-155.4W+ #Chan–Lam #Pinacol #Amination
Highly Discriminative and Chemoselective DeprotectionAcetals are the most useful protecting groups for carbonyl functional groups. In addition to the r...有机方法2019-06-293.9W+
Systematic Evaluation of 2-Arylazocarboxylates and 2-Arylazocarboxamides as Mitsunobu Reagents2-Arylazocarboxylate and 2-arylazocarboxamide derivatives can serve as replacements of typical Mit...有机方法2019-05-033.9W+
Synthesis of Nitroolefins and Nitroarenes under Mild Conditions1,3-Disulfonic acid imidazolium nitrate {[Dsim]NO3} was prepared and characterized as a new ionic...有机方法2019-04-153.4W+
MIDA Boronates(Burke硼酸酯)Burke硼酸酯可起到与B-保护的卤硼酸一样的作用而用于各种多重交叉偶联反应。使用温和的水相NaOH、NaHCO3为碱时可释放出相应的硼酸。Burke硼酸酯可兼容许多合成试剂,能用于将简单的含硼起始原...有机方法2019-04-066.0W+
一种实用的还原胺化还原剂2-甲基吡啶硼烷醛(酮 一锅还原胺化是有机化学中的一个重要反应,常用的还原剂有NaBH3CN、NaBH(OAc 3、吡啶硼烷络合物等。文献中有报道吡啶硼烷络合物环境友好,可以避免NaBH3CN在产品或后处理中产生氰化...有机方法2019-04-056.2W+
Amination of Arylboronic Compounds via the Copper-Catalyzed Addition of Arylboronic Esters Arylboronic esters add to di-tert-butyl azodicarboxylate under mild reaction conditions (at room t...有机方法2019-02-184.2W+
Desulfonylative Methenylation of β-Keto SulfonesA one-step strategy for the synthesis of α-methenyl ketones from β-keto sufones is reported. Succe...有机方法2019-01-053.6W+
Cy*Phine Ligand for Efficient Cross-Coupling Common namePd(Cy*Phine 2Cl2Assay95%CAS #1668598-24-0Molecular FormulaC78H106Cl2P2PdMolecular Weight1...有机方法2018-11-055.5W+ #Sonogashira
Efficient Synthesis of α-Aryl EstersA catalytic amount of Pd(dba 2 ligated by either carbene precursor N,N‘-bis(2,6-diisopropylphenyl -4...有机方法2018-05-253.7W+